Ionic liquids as a novel solvent for lanthanide extraction.

نویسندگان

  • Kazunori Nakashima
  • Fukiko Kubota
  • Tatsuo Maruyama
  • Masahiro Goto
چکیده

Octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) dissolved in an ionic liquids, 1-butyl-3-methyl-imidazolium hexafluorophosphate, greatly enhances extractability and selectivity of lanthanide cations compared to that dissolved in conventional organic solvents; further, the recovery of lanthanides extracted into ionic liquids can be accomplished using several stripping solutions containing complexing agents. The possibility of utilizing ionic liquids as novel separation media in an industrial liquid-liquid extraction process was demonstrated.

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عنوان ژورنال:
  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

دوره 19 8  شماره 

صفحات  -

تاریخ انتشار 2003